Cadmium acetate

Cadmium acetate
Identifiers
CAS number 543-90-8 Y
[5743-04-4] (dihydrate)
PubChem 10986
ChemSpider 10521 Y
EC number 208-853-2
RTECS number AF7505000
Jmol-3D images Image 1
Properties
Molecular formula Cd(CH3COO)2 (anhydrous)
Cd(CH3COO)2·2H2O (dihydrate)
Molar mass 230.500 g/mol (anhydrous)
266.529 g/mol (dihydrate)
Appearance colorless crystals (anhydrous)
white crystals (dihydrate)
Density 2.341 g/cm3 (anhydrous)
2.01 g/cm3 (dihydrate)
Melting point

255 °C (anhydrous)
decomposes at 130°C (dihydrate)[1]

Solubility in water soluble in water, methanol, ethanol (anhydrous)
very soluble in water, soluble in ethanol (dihydrate)
Hazards
R-phrases R20/21/22
S-phrases (S2) S22[2]
NFPA 704
1
3
0
Related compounds
Other anions Cadmium fluoride
Cadmium chloride
Cadmium bromide
Cadmium iodide
Other cations Zinc acetate
Mercury(II) acetate
Silver acetate
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Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa)
Infobox references

Cadmium acetate is the chemical compound with the formula Cd(CH3CO2)2. This colourless solid is classified coordination polymer, featuring acetate ligands interconnecting cadmium centers. The compound exists in anhydrous form and as a dihydrate. It forms by treating cadmium oxide with acetic acid:[2][3]

CdO + 2 CH3COOH → Cd(CH3COO)2 + H2O

Contents

Uses

Cadmium acetate is used for glazing ceramics and pottery; in electroplating baths, in dyeing and printing textiles; and as an analytic reagent for sulfur, selenium and tellurium. [3]

Preparation

Cadmium acetate is prepared by treating cadmium oxide with acetic acid. The compound may also be prepared by treating cadmium nitrate with acetic anhydride.

Safety

Cadmium compounds are considered Group 1 carcinogens by the IARC.

References

  1. ^ Lide, David R. (1998). Handbook of Chemistry and Physics (87 ed.). Boca Raton, FL: CRC Press. pp. 447. ISBN 0849305942. 
  2. ^ a b Gangolli, S. (1999). The Dictionary of Substances and Their Effects. London: Royal Society of Chemistry. pp. 12–13. http://books.google.com/books?id=s4YittJrOsAC&pg=PA12&dq=%22Cadmium+acetate%22&as_brr=3&ei=4tzPSbj5HYfSNPL4gasE&client=firefox-a. Retrieved 2009-03-29. 
  3. ^ a b Patnaik, Pradyot (2003). Handbook of Inorganic Chemical Compounds. McGraw-Hill Professional. pp. 143–144. ISBN 0070494398. http://books.google.com/books?id=Xqj-TTzkvTEC&pg=PA243&dq=%22Cobalt+hydroxide%22+OR+%22Cobalt(II)+hydroxide%22&as_brr=3&ei=oI_NSeKSPJWOyAT5k7HWBQ&client=firefox-a. Retrieved 2009-03-29.